Feldspars

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Mineral class:Tectosilicate
Composition:Feldspars are aluminum silicates with varying proportions of potassium (K), sodium (Na) or calcium (Ca). There are two broad categories of feldspars:

  1. Potassium feldspars, KAlSi3O8. Potassium feldspars are polymorphic, displaying different crystal forms despite having the same chemical composition. They are also called potash or alkali feldspars.
    • Orthoclase. Usually colorless or white. Monoclinic crystals. When mixed with quartz and kaolin fuses at a relatively low temperature to form porcelain.
    • Microcline. Triclinic crystals. White or pink colors are common. A blue-green variety is called Amazonite, found in Brazil, India, and at Pike's Peak, Colorado.

  2. Plagioclase feldspars are sodium/potassium aluminum silicates, with potassium and sodium ions instead of calcium. They form a solution series from Albite (all sodium) to Anorthite (all calcium), where intermediate members of the series each have increasing concentrations of calcium and decreasing amounts of sodium:
    1. NaAlSi3O8 = Sodium feldspar is Albite.
    2. Oligoclase, (Na, Ca)AlSi3O8
    3. Andesine, (Na, Ca)AlSi3O8
    4. Labradorite, (Ca, Na)AlSi3O8
    5. Bytownite, (Ca, Na)AlSi3O8
    6. CaAl2Si2O8 = Calcium feldspar is Anorthite.
Hardness:6
Color:White, pink, grey, green
Streak:White
Cleavage:2 directions at 90 degree angles. Orthoclase cleavage surfaces are striated; plagioclase surfaces are not striated.
Environment:Feldspars account for 60 percent of the continental crust, but are virtually absent from ocean beds. Common in stream gravel.
Comments:Scratched by quartz but not by knife.

At the surface of the Earth, particularly in warm, humid environments, feldspars weather (by hydrolysis) to form Kaolin, a fine-grained, white clay which is the main ingredient of Kaopectate. The large positive ions of the feldspars (K+, Na+, Ca2+) are replaced by hydrogen ions (H+) from water, yielding Al2Si2O5(OH)4. Kaolin is found as bedded masses in soils and sedimentary rocks. It is soft (Mohs 2.5 or less) and has an earthy odor, particularly if moistened.